EUU, Alm.del - 2022-23 (2. samling) - Supplerende svar på spørgsmål 49: Spm. om, hvilke interessenter, virksomheder mv. ministeriet har været i dialog med i forbindelse med ønsket om at indføre et forbud imod anvendelsen af PFAS, til miljøministeren, kopi til udenrigsministeren

Europaudvalget 2022-23 (2. samling)
EUU Alm.del
Offentligt

Brussels, xx October 2021

To Whom it May Concern:

3M Corporation

appreciates the opportunity to participate in the

2

nd

Stakeholder Consultation on a Restriction for PFAS.

1

We also appreciate the opportunity to

comment on the

for the various PFAS use categories.

st

3M has been an active participant in the stakeholder consultations, from the First

Call

for Evidence in July 2020 through present day. 3M has submitted twelve responses in the 1

st

Call for Evidence in July 2020 (see Table 1) as well as thirteen use-specific studies from

October 2020 through May 2021 (see Table 2). In October 2021, 3M provided responses to

eleven of the categories during the 2

nd

Call for Evidence (see Table 3). A summary of

submissions is listed below. These submissions are readily available and may be re-submitted

at the request of the authorities.

Table 1:

3M submitted 12 individual responses during the 1st Call for Evidence (July

2020), providing information according to individual product lines and with inputs from

various 3M reporting units:

1)

3M Fluorinert, 3M Performance Chemicals and 3M-branded fluids

(by 3M

Transportation & Electronics)

2)

3M Novec-branded fluids

(by 3M Transportation & Electronics)

3)

3M Fluoropolymers: Fluoroplastics Dispersions

(by 3M Transportation & Electronics)

4)

3M Fluoropolymers: Solid Fluoroplastics

(by 3M Transportation & Electronics)

5)

3M Fluoropolymers: Fluoroelastomers

(by 3M Transportation & Electronics)

6)

3M Fluoropolymers: Polymer Processing Additives

(by 3M Transportation &

Electronics)

7)

3M Specialty Chemicals

(by 3M Transportation & Electronics)

8)

3M PFAS-enabled products: PFAS for Product Release Liners

(by 3M Healthcare, 3M

Safety & Industrial, and 3M Consumer)

9)

3M PFAS-enabled products: PBSF-Enabled Fluorosurfactants - Acrylic Foam Tapes

(by 3M Safety & Industrial and 3M Transportation & Electronics)

10)

3M PFAS-enabled products: PBSF-Enabled Fluorosurfactants

(by 3M Healthcare, 3M

Safety & Industrial, 3M Transportation & Electronics, and 3M Consumer)

11)

3M PFAS-enabled products: PBSF-Enabled Coatings

(by 3M Safety & Industrial, 3M

Transportation & Electronics, and 3M Consumer)

12)

3M PFAS-enabled products: Other PFAS and PFAS Mixture Based Coatings

(by 3M

Healthcare, 3M Safety & Industrial, and 3M Transportation & Electronics)

Table 2:

3M provided information to 13 use-specific studies conducted by the five

countries (and respective consultants) between October 2020 and May 2021:

1. 3M Response to de Milieutafel on PFAS in Medical Devices and Pharmaceuticals

2. 3M Response to RPA on PFAS Manufacturing

3. 3M Response to Exponent on PFAS in Data center Immersion Cooling

4. 3M Response to Exponent on PFAS & F-gases

1

Survey Powered by Webropol: 2nd Stakeholder Consultation on a Restriction for PFAS (webropolsurveys.com)

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EUU, Alm.del - 2022-23 (2. samling) - Supplerende svar på spørgsmål 49: Spm. om, hvilke interessenter, virksomheder mv. ministeriet har været i dialog med i forbindelse med ønsket om at indføre et forbud imod anvendelsen af PFAS, til miljøministeren, kopi til udenrigsministeren

5. 3M Response to Exponent on PFAS Fire Suppression Manufacturers and Users

6. 3M Response to Exponent on PFAS in Food and Feed Equipment

7. 3M Response to Exponent on PFAS in Kitchenware

8. 3M Response to Exponent on PFAS in Packaging Food and Non-Food

9. 3M Response to HaskoningDHV on PFAS in Electronics and Energy Industry

10. 3M Response to BAUA on PFAS in Transport and Lubricants & Greases

11. 3M Response to Wood on PFAS in Textiles (for PPE and Medical Device products)

12. 3M Response to Wood on PFAS in Petroleum and Mining Sector

13. 3M Response to Wood on PFAS in Construction products

Table 3:

3M provided response to Section A-E (as applicable) via the online portal for the

below 11 category-specific components of the questionnaire on 17 October 2021. 3M

1. 3M Response to TULAC

2. 3M Response to Medical Devices

3. 3M Response to Electronics and Energy

4. 3M Response to Construction

5. 3M Response to PFAS Manufacturing

6. 3M Response to Transportation

7. 3M Response to Lubricants

8. 3M Response to Waste

9. 3M Response to Food Contact

10. 3M Response to Manufacturing

11. 3M Response to F-Gas

Based on 3M

s, we would like to highlight data gaps in the investigation

report summaries, including missing uses and applications, missing PFAS substances, or

wrongly stated information.

The information below serves as a 3M-only data-gap analysis for the authorities regarding the

accuracy and completeness of these reports based on the information provided. When

developing the PFAS restriction dossiers, 3M would ask that the authorities consider

corrections to the reports. 3M recognizes the significant effort and complexity of

consolidating many responders input and would welcome the opportunity to further discuss

3M believes regulatory decisions should be grounded in sound science. 3M remains

committed to sharing all available and relevant information to help inform the understanding

of the five countries preparing the PFAS restriction proposal.

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EUU, Alm.del - 2022-23 (2. samling) - Supplerende svar på spørgsmål 49: Spm. om, hvilke interessenter, virksomheder mv. ministeriet har været i dialog med i forbindelse med ønsket om at indføre et forbud imod anvendelsen af PFAS, til miljøministeren, kopi til udenrigsministeren

DATA GAP ANALYSIS

LUBRICANTS:

:

T

-03-1) should be added to the

list of carrier solvents.

The products

Engineered Fluid (CAS# 163702-08-7/163702-07-

6) and

Engineered Fluid (CAS# 63702-06-5/163702-05-4) also

used as carrier solvents are included in the report.

The summary report section 4 Emissions, Table 3 estimates that 35 tonnes of PTFE

(Micropowder) are emitted to air annually and 31 tonnes to water. As PTFE is not

volatile and insoluble in water, it is unclear how the report could reach this conclusion.

Similar partitioning is applied to PTFE (granulates) and PFPE which raised comparable

questions regarding the conclusion of this section.

Section 4.1, Table 5 notes that the justification for application of emission factors

unknown from our experience and appears not be a reasonable assumption. The

reasonable assumption due to the lack of volatility of these substances and lack of

water solubility. Spills or leaks in filling are manageable and are unlikely to result in

uncontrolled emissions to air or water as noted in the table.

The lack of volatility and water solubility of most of the higher molecular weight

backbone fluoropolymers leads to emissions that are overstated and appear to

partition too heavily to air and water.

PETROLEUM AND MINING

:

The summary report does not include use of PFAS in the Chemical Processing

Industries (CPI) which also extensively use PFAS, and particularly backbone

fluoropolymers (such as Fluoroplastics or Fluoroelastomers) in equipment like uses in

Petroleum and Mining such as seals, linings and coatings.

use, emissions and

liners, valves, O-rings, gaskets, and packer elements in the petroleum industry (Table

2.2).

CONSTRUCTION:

:

The use of foam blowing additives in the production of energy efficient building

material is missing from the current report.

188 Foam Blowing Additive (CAS #3709-71-5) in this application.

-

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EUU, Alm.del - 2022-23 (2. samling) - Supplerende svar på spørgsmål 49: Spm. om, hvilke interessenter, virksomheder mv. ministeriet har været i dialog med i forbindelse med ønsket om at indføre et forbud imod anvendelsen af PFAS, til miljøministeren, kopi til udenrigsministeren

Structural Glazing is missing from the current report. PBSF-enabled tapes are used to

attach glass panels to metal frames in curtain wall systems, commercial windows and

doors, skylight and canopy systems replacing commonly used mechanical fasteners,

gaskets and structural silicone sealants. They bond with excellent dynamic strength to

replace conventional wet glazing and resist to environmental conditions such as UV,

moisture, heat, and cold.

PBSF-enabled Architectural Panel Tapes are missing in the current report. They are

used for many applications in the construction industry, including the manufacture of

architectural panels for curtain walls, exterior building cladding and interior panel and

trim attachment. In many situations, they replace liquid adhesives, sealants, welds and

mechanical fasteners. They provide immediate handling strength during the fabrication

process and do not shrink after curing, like with some liquid applied sealants. This

shrinkage can result in isolated panel stress that may be visible on the exterior face of

the architectural panel.

Window films are missing from the current report. PBSF-enabled coatings are used in

window film applications for construction because these films deliver superior

performance over standard polyester films in blast and impact events; yet still maintain

a high level of optical clarity. The PBSF is used to aid in wetting out during the coating

step. Window films are used in both automotive aftermarket as well as in public,

commercial and residential buildings. For construction applications window films are

used for the following properties: mitigates hazards from shattered glass during natural

disasters, helps protect people from flying glass shards, one of the most common

causes of blast-related injuries and fatalities, helps increase security and provide added

protection against smash and grab burglaries, significantly blocks the amount of

harmful UV rays.

polishing should be added.

A fluorosilicone chemistry is used in release liners for silicone-based adhesives in some

home improvement applications. Two silicone-based chemistries are used in products,

one picture hanging and one for bath and outdoor products. The fluorosilicone release

chemistry is used in the manufacture of the release liner which allows the silicone-

based adhesives to be coated and converted in the form of an adhesive transfer tape to

produce the final product.

Glass - fibre impregnation by PTFE-Dispersion is missing in the current report. The

main use of this product is roofing applications as a fire-resistant, weather resistant,

self-cleaning and light-weight construction material. It is frequently used in

applications where glass is not technically viable

(https://en.wikipedia.org/wiki/Mecca_fire_of_1997;

https://www.ifai.com/2008/09/01/fireproof-tents-shelter-visitors-at-mecca/

).

ETFE and THV films are used in different construction applications due to UV-

transparency, hail and water resistance.

In the questionnaire, PTFE should be divided in the following sub-categories: moulding

powder, fine-powder, and dispersion.

Chemical

Process Industry is the second largest segment according to the Socioeconomic study

published by Plastics Europe FPG group. It is not appropriately reflected in the

summary report or questionnaires. PTFE, PFA, FEP, PVDF, THV, FKM and FFKM are all

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EUU, Alm.del - 2022-23 (2. samling) - Supplerende svar på spørgsmål 49: Spm. om, hvilke interessenter, virksomheder mv. ministeriet har været i dialog med i forbindelse med ønsket om at indføre et forbud imod anvendelsen af PFAS, til miljøministeren, kopi til udenrigsministeren

used in the construction of chemical handling facilities chemicals, pharmaceutical,

bio-tech, oil & gas and other plants. The functionality spans UV-transparency, fire-

resistance, weather resistance (e.g., hail, general weathering), resistance to harsh

cleaning chemicals or sterilization, effective corrosion prevention to creating a metal

ion free environment. PFAS-containing Polymer Processing Additives are used to help

with the defect-free extrusion of high strength HDPE

(https://multimedia.3m.com/mws/media/991385O/dynamar-ppas-in-applications-of-

hdpe-pipes.pdf

).

MEDICAL DEVICES:

:

The use of

Fluid (CAS # 297730-93-

(CAS # 1064698-37-8) should be added.

TULAC

-40

It is important to note the use of 3M Polymer Melt Additive in the medical protective

clothing & facemasks. 3M Polymer Melt Additive is a fluorochemical flake (PFBS (C4)

based fluoro-polymeric material) for incorporation into polyolefin and other synthetic

resins (e.g. polypropylene). 3M Polymer Melt Additive is heat and shear stable to a

wide variety of extrusion conditions. 3M Polymer Melt Additive is designed to be

compatible with synthetic resins at extrusion temperatures. Consequently, the additive

can localize at the surface during quenching or within a few hours to provide an

effective surface-active treatment, while not significantly influencing fiber properties.

The report references personal protective equipment (PPE) several times, but a dedicated

section or category would be appropriate to include the following products should be added:

system control unit, Protective Coveralls 4532+, high performance filtration applications,

valves, washers, o-rings and electrical components with coated wires, used in multiple 3M

Scott Fire & Safety products.

PFAS PRODUCTION (MANUFACTURING)

In the category PFAS production (manufacturing), the following substances should be added:

Manufactured in EU/sold in EU+UK =

-40 (CAS

#1064698-37-

FC770 (CAS #1093615-61-

2),

Fluid PF5056 (2187449-42-7),

Fluid PF5058

(CAS# 2176446-38-

FA-188 Foam Blowing Additive (CAS #3709-71-5);

Imported into EU/sold in EU+UK =

-03-

1),

Engineered Fluid (CAS# 163702-08-7/163702-07-6)

and

Engineered Fluid (CAS# 63702-06-5/163702-05-4).

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EUU, Alm.del - 2022-23 (2. samling) - Supplerende svar på spørgsmål 49: Spm. om, hvilke interessenter, virksomheder mv. ministeriet har været i dialog med i forbindelse med ønsket om at indføre et forbud imod anvendelsen af PFAS, til miljøministeren, kopi til udenrigsministeren

F-GASES

-

:

The use of foam blowing additives in the production of energy efficient building

material should be added.

-188 Foam

Blowing Additive (CAS #3709-71-5) in this application.

The use of fluoroketone is missing as a clean agent fire suppression fluid, specifically

756-13-8).

The application of cover gas is detailed, however, the use of fluoroketone is missing as

a

756-

13-8).

The following product listed in F-Gas Annex I is missing:

Liquid FC-72 (CAS# 1064697-81-9). This product is typically used as a heat transfer

agent. Other products used as heat transfer agents are:

Liquid FC-3283 (CAS# 338-83-

-40 (CAS#

1064698-37-

-770 (CAS# 1093615-61-2).

The electrical equipment application is mentioned but the use of alternatives to sulfur

hexafluoride (SF

6

) in electrical switchgear, gas insulated lines and other gas-insulated

equipment is missing.

Insulating Gas (CAS # 756-12-

4710 Insulating Gas (CAS # 42532-60-5) as low global warming potential alternatives

to sulfur hexafluoride in this application.

The preservation of documents application should be added. The products used in

-08-

7/163702-07-

-5060 (CAS# 1064697-81-9).

Specific F-gas (specific composition is confidential) is used as explosion tamer in

polymerization processes during the production of fluoropolymers. CAS # can be

shared confidentially.

ELECTRONICS & ENERGY

:

The use of alternatives to sulfur hexafluoride (SF

6

) in Energy in electrical switchgear,

gas insulated lines and other gas-insulated equipment is missing. In particular, the

summary report and the questionnaire do not mention the use of fluorinated ketone

756-12-

42532-60-5) as low global warming potential

alternatives to sulfur hexafluoride in this application.

The following substances should be added under fire protection fluid:

1230 Fire Protection Fluid (CAS # 756-13-8).

The following substances should be added under Coatings of electronic

components:

(2-10% trade

secret fluoroaliphatic

Engineered

Fluid (CAS# 163702-08-7/163702-07-6)).

The following substances should be added under Heat transfer fluids:

7200 Engineered Fluid (CAS# 63702-06-5/163702-05-4),

7700 Engineered Fluid (CAS# 957209-18-6),

-

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EUU, Alm.del - 2022-23 (2. samling) - Supplerende svar på spørgsmål 49: Spm. om, hvilke interessenter, virksomheder mv. ministeriet har været i dialog med i forbindelse med ønsket om at indføre et forbud imod anvendelsen af PFAS, til miljøministeren, kopi til udenrigsministeren

3283 (CAS # 338-83-0)

756-13-

8). Other heat transfer fluids included in the report are:

Engineered Fluid (CAS# 297730-93-9),

-40

(CAS# 1064698-37-8) and

-72 (CAS#

1064697-81-9.

The following substances should be added under Solvent/Solvent Cleaning of

Electronics Components:

-08-

7/163702-07-6),

Engineered Fluid (azeotropic blend of

Isopropanol with

Engineered Fluid CAS# 163702-08-7/163702-

07-6),

(azeotropic blend of trans-1,2-

dichloroethylene (t-DCE)

(CAS # 132182-

92-4)).

The following substances should be added under Lubricant deposition for use as

solvents:

Engineered Fluid (CAS# 163702-08-7/163702-07-

6) and

Engineered Fluid (CAS# 63702-06-5/163702-05-4).

The following substances should be added under Thermal testing:

Electronic Liquid FC-770 (CAS# 1093615-61-2) and

Liquid FC-40 (CAS# 1064698-37-8).

The following substances should be added under Data Centers immersion cooling of

semi devices/servers:

-3284 (CAS# 382-28-

5 ),

-3283 (CAS# 338-83-

Electronic Liquid FC-40/43 (CAS #1064698-37-8),

Liquid FC-72 (CAS# 382-28-

-03-

1),

-08-7/163702-07-6) and

(CAS# 756-13-8).

The following products for fluoropolymer tube lining, solar films, cable and wire

insulation should be added: PFPE (CAS# 69991-67-9) lubricant is used on silicone

cable accessories, Silicone rubber compound containing PTFE (CAS# 9002-84-0) is

used in molding and extruding cable accessories; Solar Radiative Film uses PVDF

(CAS# 24937-79-9); Heat shrink tubing with PVDF (CAS# 24937-79-9).

The following sub-use category should be added: Ion exchange membrane in

vanadium redox batteries. Ion exchange membrane in vanadium redox batteries, made

out of fluoropolymers, are used as sealings for aggressive chemicals. Seals in high

temperature stationary fuel cells use fluoropolymer seals due to corrosion and

temperature resistance.

The summary report does not mention a small but growing application of the use of

Polymer Optical Fibers for data transmission where electromagnetic interference is a

concern. The fluoropolymer serves as a low refractive index layer.

-based

films and coatings are being used, but also PFAS-based tapes are heavily used in the

bonding of solar panels.

TRANSPORTATION

:

The report says that no information is available on fire prevention and protection. The

following substance should be added as a fire protection fluid:

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EUU, Alm.del - 2022-23 (2. samling) - Supplerende svar på spørgsmål 49: Spm. om, hvilke interessenter, virksomheder mv. ministeriet har været i dialog med i forbindelse med ønsket om at indføre et forbud imod anvendelsen af PFAS, til miljøministeren, kopi til udenrigsministeren

Fire Protection Fluid (CAS # 756-13-8)

.

Specific application includes fire systems for

marine vessels.

heat transfer fluids in immersion cooling applications in automotive electronics

applications (e.g. inverters, Electronic Control Unit (ECUs), on-board chargers, traction

motors). The following substances should be added as heat transfer fluids for power

electronics cooling:

-08-

7/163702-07-

132182-92-

neered Fluid (CAS# 297730-93-

Fluid (CAS# 756-13-

-770 (CAS# 1093615-

61-2),

-72 (CAS# 1064697-81-9).

th the Novec engineered

fluids used as solvent are used in automotive electronics to coat the printed circuit

boards and LED lighting for moisture and corrosion protection. Novec fluids can also

be used as carrier solvents for anti-fingerprint or anti-smudge coating materials for

automotive display surface coatings. The following substance should be added as a

-10% trade

secret fluoroaliphatic

7100 (CAS

# 756-13-8)).

The following substances should be added

Engineered Fluid (CAS# 163702-08-7/163702-07-6) and Novec 71DE

fluid (azeotropic blend of t-DCE with Novec 7100 fluid (CAS# 163702-08-7/163702-

07-6), Novec 71IPA fluid (azeotropic blend of Isopropanol and Novec 7100 fluid

(CAS# 163702-08-7/163702-07-6), Novec 72DE fluid (azeotropic blend of t-DCE

with Novec 7100 fluid (CAS# 163702-08-7/163702-07-6) and Novec 7200

fluid (CAS# 63702-06-5/163702-05-4), and Novec 73DE fluid (an azeotropic blend of

t-DCE and Novec 7300 fluid (CAS # 132182-92-4)).

The following substances should be added as solvents

-03-1),

163702-08-7/163702-07-

-06-

5/163702-05-4).

The following substances should be added as testing fluids:

Electronic Liquid FC-3284 (CAS# 382-28-5),

-

40 (CAS# 382-28-5),

-72 (CAS# 382-28-5).

Summary report mentions the use of PFAS-enabled adhesive tapes as paint

replacement. To be added: adhesive tapes are also used for paint protection. Paint

protection film products use PFAS as a stabilizing agent for the polymer that goes into

making of the finished product. The finished product itself is affixed to key areas of a

vehicle exterior to protect the painted surface from chips caused by impinging debris

and rocks. Other adhesi

utilizes a fluoropolymer film layer that provides weatherability and reduces the

potential of corrosion between two dissimilar materials that the SIT2010 is positioned

between in the vehicle chassis.

Summary report rightly mentions that Acrylic Foam Tape (AFT) products (PFAS are

used as stabilizing agent in production of tape) are used to affix the weight to the

wheel surface. To be added: The finished AFT product is also used to affix

components such as molding, clips and emblems to the exterior surface of the vehicle,

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as well as in the vehicle interior to affix sensors to the windshield for the rearview

mirror assembly, as well as for affixing silicone seals in the doors and trunk lids. AFT

products use PBSF as a manufacturing process aid, therefore the PBSF should be

added as a PFAS substance used in manufacturing of transportation products and

articles. Without its use the final product does not consistently meet quality and

performance requirements as defined by the automotive sector.

Summary report rightly mentions the use of adhesive tapes on aircraft exterior to

provide a chemical resistant surface for the aircraft as well as to reduce

surface energy. To be added, Polyurethane Protective tape is also used on the interior

of an aircraft. The fluoropolymer is incorporated in the polyurethane, which helps the

product to provide a moisture resistant barrier that helps to reduce the potential for

corrosion on the aircraft interior surface where it is applied.

Summary report mentions a group of fluoroelastomers as well as perfluoropolymeric

ionomers as part of PFAS substances used in transportation products and articles, but

does not mention other fluoropolymers, such as fluoroplastics and FKM and FFKM.

Fluoroplastic wiring is used in high temperature wiring to the catalytic converter as

well as used under the hood wiring applications for smaller and hotter engines. High

temperature FKM and FFKM seals are used in aerospace, commercial vehicles and

cars. Examples of applications that require high temperature performance combined

with chemical resistance are the cylinder head gasket, air intake manifold and turbo

charger hoses.

Additionally, PTFE Micropowders are also used as additives in oil-based lubricants and

in dry lubricants. The technical function is to reduce friction and to reduce the

temperature dependence of the lubricant formulation. Two critical applications of

PFAS containing lubricants include dry lubricants or PTFE bearings, which are

frequently used in durability and safety-relevant parts, and these applications are

nearly maintenance-free in accessibility-challenged environments. Also,

carrier solvents for dry lubricants (e.g.

PTFE powder) that are added to plastics used in automotive interiors.

It should be noted that fluoropolymers are essential to meet Euro 6 requirements for

standard and ethanol-containing fuel grades.

One missing subgroup within the Transportation summary report is wirings. Wiring for

catalytic converter sensors are commonly made from PTFE, and under-the-hood

wiring use Fluorothermoplastics where high temperature resistance is required (near

the Internal Combustion Engine). Fluoropolymers are also required in aircraft wiring

due to temperature and chemical resistance. Some aircraft wiring is inside of the

Kerosene tanks (wings) and therefore constantly exposed to fuel. Fluoropolymer

sleeves or jacketing provides the safety required.

Window films are missing from the current report. PBSF-enabled coatings used in

commercial/residential building window films are missing in the current report. The

PBSF is used to aid in wetting out during the coating step. Window films are used in

both automotive aftermarket as well as in public, commercial and residential buildings.

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FOOD CONTACT MATERIALS AND PACKAGING

The summary report characterizes Gen-X as a polymer processing aid (PPA). Gen-X is

a fluorinated emulsifier which is different from a polymer processing additive. We

believe there is a risk of confusion between this terminology, equating polymer

processing aid and the polymer processing additive. Polymer Processing Additives are

fluoropolymer-based additives to polyolefins, and engineering polymers to enable or

improve film, tubing, fibers or pipe extrusion or blow molding processes.

A missing sub-category under the consumer cookware applications are P Electrostatic

Powder Coating grades. Powders designed for electrostatic powder spray-coating are

used to produce non-stick coatings for industrial cook and backware as well as

industrial and consumer use rice cookers.

Under industrial applications, it should be noted that seals, O-rings, gaskets, tubing and

pipes use Fluorothermoplastics and PTFE that are processed into pipes and tubing for

commercial food and feed products or equipment for the private household.

Fluorothermoplastics and PTFE are also processed into valves and fittings for

commercial food and feed products. Fluoropolymer dispersions are formulated into

coatings for belts for commercial food and feed products.

Fluorelastomers designed for food contact applications such as seals that require high

temperature and chemical stability (frequently aggressive cleaning chemicals) cannot

be provided by other materials. Likewise, Fluorothermoplastics, PTFE and PTFE

compounds used for seals, valves and tubing that require high temperature, stability

against steam and chemicals (frequently aggressive cleaning chemicals) cannot be

provided by other materials.

The Polymer Processing Additives enable some of the recent reduction of packaging

film needed. They are not intended to change the surface properties of the packaging

material, but help to reduce or eliminate processing defects, improve processing

efficiency, improve energy efficiency and reducte manufacturing waste. Typically,

fluoroelastomers or fluorothermoplastics are used as Polymer Processing Additives

(not low molecular weight additives). Polymer Processing Additives are frequently

formulated with inorganics and non-fluorinated aliphatic polyethers or polyesters as

synergists.

Polymer Processing Additives are used in packaging. Fluoropolymers used in Polymer

Processing Additives are fluoroelastomers and fluorothermoplastics, so high-molecular

weight fluoropolymers. The summary report is incorrectly reporting their use,

especially in the food packaging sub-category.

Polymer Processing Additives promotes down gauging of films, layer stability in

multilayer construction, less waste in manufacturing, and less energy needed for

operations (enable overall lower cost in manufacturing). In exchange, they enable

affordable food packaging, help enable usage of strong, thin, light-weights packaging

articles, reduce overall consumption of plastic, enable preservation of food freshness,

reduce food waste and help enable increased recycled contact into packaging.

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EUU, Alm.del - 2022-23 (2. samling) - Supplerende svar på spørgsmål 49: Spm. om, hvilke interessenter, virksomheder mv. ministeriet har været i dialog med i forbindelse med ønsket om at indføre et forbud imod anvendelsen af PFAS, til miljøministeren, kopi til udenrigsministeren

OTHER: USES NOT COVERED BY THE STUDIES/QUESTIONAIRES

3M also uses PFAS in some of our Personal Protective Equipment that is not covered

by the TULAC study and questionnaire, including:

PELTOR

T

communications headset and system control unit, Protective

Coveralls 4532+, high performance filtration applications, Valves, washers, o-rings and

electrical components with coated wires, used in multiple 3M Scott Fire & Safety

products.

3M supplies products using PFPE and other PFAS for Release Liners to the industrial

converters and users in the general industrial and electronics industry. PFAS-enabled

silicone adhesives are used in double coated tapes, adhesive transfer tapes and foam

tapes. They are also used in bonding applications in mobile handheld devices and other

electronic devices. PFPE is used to coat the liner and provide the proper surface to

protect the adhesive prior to use. It provides excellent flexibility, high temperature

resistance and consistent performance over wide temperature ranges.

-group is home improvements

products (i.e., foam mounting tapes and squares, and damage-free hanging solutions).

A fluorosilicone chemistry is used in release liners for our silicone-based adhesives in

some home improvement applications. Two silicone-based chemistries are used in

products, one picture hanging and one for bath and outdoor products. The

fluorosilicone release chemistry is used in the manufacture of the release liner which

allows the silicone-based adhesives to be coated and converted in the form of an

adhesive transfer tape to produce the final product.

PBSF coating is used in whiteboard films to provide stain resistant properties. This

help

films can be applied to a variety of substrates and can be directly applied to a wall,

table or as a replacement film over an existing whiteboard.

OTHER: WRONG STATEMENTS:

It should be noted that there is an error in Appendix 1

-gas

-heptene

MPHE Sion TM is NOT a

fluoroketone.

Inconsistencies in the terminology used in the summary report:

and fluorinated Processing Aid are used in confusing and inconsistent ways in the

summary reports. A

clear definition of these terms is critically needed.

There are limitations to apply ERC approaches to calculate the emissions due to the

lack of volatility and water solubility of most of the higher molecular weight

fluoropolymers. It will be appropriate to develop Specific Environmental Release

Categories (SPERCs) for subsets of PFAS used in individual categories that better

consider the applications and material characteristics for PFAS materials or subsets of

PFAS (i.e. fluoropolymers, etc.). Therefore, the ERC analysis report should be adjusted

taking into consideration the physical properties and use conditions of PFAS.

In the use Category F-gas, the Section C solvent sub-use alternatives table lists several

non-PFAS alternatives. These same non-PFAS solvent alternatives are also reported in

Appendix 8 of the report Report summary F gas uses july 2021 This report and the

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EUU, Alm.del - 2022-23 (2. samling) - Supplerende svar på spørgsmål 49: Spm. om, hvilke interessenter, virksomheder mv. ministeriet har været i dialog med i forbindelse med ønsket om at indføre et forbud imod anvendelsen af PFAS, til miljøministeren, kopi til udenrigsministeren

listed alternatives are directly contradicted by the contents of the

of Fluorinated Gases (F-Gases) in the European Economic Area, also provided by the

authorities, questioning the viability of these options. Paragraph 4.3.2 of this report

cleaning: isopropyl alcohol (IPA), n-propyl bromide (nPB), dichloromethane

(DCM,methylenechloride),trans-1,2-dichloroethylene,trichloroethylene (TCE),

perchloroethylene (PER), volatile methyl siloxanes, hydrocarbons (hexane, heptane,

benzene) and acetone. Many of these alternatives have health concerns and regulatory

restrictions. Other alternatives such as IPA are considered highly flammable and

therefore not suitable for some uses. In fact as referenced by (EC) No 1272/2008 on

the classification, labelling and packaging of substances and mixtures (CLP Regulation)

the listed alternative solvents present significant flammability and human health

concerns and may further include regulatory barriers preventing their use: Isopropyl

alcohol (67-63-0) is a category 2 highly flammable liquid/vapor, N-propyl bromide

(106-94-5) is a category 1B reproductive toxin and is further subject to Authorization in

the EU under REACH Annex XIV, dichloromethane (75-09-2) is a category 2

carcinogen, trans-1,2-dichloroethylene (156-60-5) is a category 2 highly flammable

liquid/vapor, trichloroethylene (79-01-6) is a category 1B carcinogen and category 2

mutagen and is further identified as an SVHC for its carcinogenic potential,

perchloroethylene is a category 2 carcinogen, octamethylcyclotetrasiloxane (CASRN

556-67-2), a volatile methyl siloxane, is a category 2 reproductive toxin and is SVHC-

listed on the basis of its PBT and vPvB characteristics, n-hexane (110-54-3) is a

category 2 highlight flammable liquid and vapor and is a category 2 reproductive toxin,

benzene (71-43-2) is a category 1A carcinogen and a category 1B mutagen and a

category 2 highly flammable liquid/vapor, heptane (142-82-5) is a category 2 highly

flammable liquid/vapor, and acetone (67-64-1) is a category 2 highly flammable

liquid/vapor.

Immersion cooling, t

-phase liquid immersion cooling

showed promising results in the, important, energy saving of datacentres. It is more

energy-efficient however, the potential for emissions is deemed higher (reference 18).

In 2016 the cost of the fluids alone was found to be higher than the cost reduction

quantitative representation of emissions. There are installations with reported

evaporative fluid losses of 1-2% per year as well as documented reports of ~1% fluid

loss per year, as reference (https://146a55aca6f00848c565-

a7635525d40ac1c70300198708936b4e.ssl.cf1.rackcdn.com/images/9f425f33160ad

cab98bfaca87c06c1ff0c71d9a3.pdf)

3M is aware of some system integrator tank

suppliers providing warranties for 1% or lower loss of fluid per year. We believe that the

industry can achieve evaporative losses on the order of 0.1% per year with ongoing

improvements to both tank design and operational controls (i.e., methods to perform

routine maintenance.) Also, while Reference 19 is a comprehensive report, it should be

considered that the work was published in 2016 and describes fluid loss and energy

consumed during a 10-month timeframe based on a single, hand-built, experimental

tank. As 3M has firsthand knowledge of the installation and operation of the

referenced system, we know that circumstances of the project forced the tank to

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EUU, Alm.del - 2022-23 (2. samling) - Supplerende svar på spørgsmål 49: Spm. om, hvilke interessenter, virksomheder mv. ministeriet har været i dialog med i forbindelse med ønsket om at indføre et forbud imod anvendelsen af PFAS, til miljøministeren, kopi til udenrigsministeren

remain open in an unsealed state for an extended period of time (i.e., days) leading to

losses far higher than is expected (and now demonstrated) in current documented

installations. The equipment used is not well described, however, it is known that in

2015/2016 when this work was completed, there were no commercially available

systems for two phase immersion cooling. In the past 5 years there have been

significant learnings and advancements to operating two phase immersion cooling

systems for use in datacenters as well as the availability of commercial systems from

multiple suppliers. Improved system design combined with operational standards

support greatly improved fluid losses resulting in losses of 1% or less over extended

periods of time. A more holistic view of the true value and cost of immersion cooling

should consider cost on the scale of an entire datacenter, including annual savings for

water and energy. Datacenters built for immersion cooling can be built in less time,

require a smaller footprint, use less water and less energy to provide equal or greater

computing power compared to an air-cooled datacenter. To take from a published

example, reference (www.opencompute.org/files/Open-Compute-Engineering-

Workshop-3M-Immersion-Cooling-March-2018-FINAL.pdf)

3M appreciates

missing uses and applications,

missing PFAS substances, or wrongly stated information in the reports when developing the

PFAS restriction dossiers.

3M welcomes the opportunity to further discuss any previously provided or above input.

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